I love every James Bond movie ever made. Pure mental bubblegum, but so freakin' what? Everey Bond has been good in their own way, too. I am not a purist.
The best? "You Only Live Twice" Ernst Stavro Blofeld as the ultimate white cat stroking bad guy, and the coolest supervillain hideout EVER in cinema! A phony volcano is both totally implausible and badass at the same time! There is also a fight between 007 in his mini helicopter and 4 or so bad guy helicopters that is pure fun
Honorable Mention
Thunderball The first movie I ever saw by myself! Emilio Largo is a great villain, complete with eye patch, his Hydrofoil is great, and the huge speargun fight at the end is pure magic.
From Russia with Love Very early Bond, but a great flick. Excellent gun battle at the gypsey camp, and Rosa Kleb is a totally unlovable villain - complete with poison spiked granny shoes!.
For Your Eyes Only The best Roger Moore Bond movie; Almost nothing could be cooler than the attack on the Greek monastery, as James Bond scales an impossible cliff, in the face of an especially stupid SPECTRE guard